Chemical Reaction Engineering
In the hydrodealkylation of toluene to benzene, the following reactions occur:C₇H₈ + H₂ → C₆H₆ + CH₄2C₆H₆ ⇋ C₁₂H₁₀ + H₂Toluene and hydrogen are fed to a reactor in a molar ratio 1:5.80% of the toluene gets converted and the selectivity of benzene(defined as moles of benzene formed/moles of toluene converted) is 90%. The fractional conversion of hydrogen is

0.152
0.16
0.144
0.136

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Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Surface reaction between absorbed A and absorbed B
Surface reaction between A in the gas phase and absorbed B
Desorption of C
Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase

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