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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
In an irreversible process

DE - dW - Tds = 0
Tds = dE - dW = 0
Tds - dE + dW< 0
Tds - dT + dW< 0

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Chemical Engineering Thermodynamics
Those solutions in which there is no volume change upon mixing the components in the liquid state and which, when diluted do not undergo any heat change (i.e. heat of dilution is zero), are called __________ solutions.

Isotonic
Ideal
None of these
Real

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Chemical Engineering Thermodynamics
If heat contents of CH₄, C₂H₄ and C₃H₈ are -17.9, 12.5 and -24.8 kcal/mole respectively, than ΔH for the reaction CH₄(g) + C₂H₄(g) ⇋ C₃H₈(g) will be __________ Kcal.

-55.2
-30.2
55.2
-19.4

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Chemical Engineering Thermodynamics
The activity of an ideal gas is numerically __________ its pressure.

More than
Less than
Equal to
Data insufficient, can't be predicted

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Chemical Engineering Thermodynamics
For a reversible process involving only pressure-volume work

(dF)T, p < 0
(dF)T, p = 0
(dF)T, p > 0
(dA)T, v < 0

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Chemical Engineering Thermodynamics
Entropy, which is a measure of the disorder of a system is

All of these
Independent of pressure
Independent of temperature
Zero at absolute zero temperature for a perfect crystalline substance

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