Chemical Engineering Thermodynamics
Gibbs-Duhem equation

Applies only to binary systems
States that n₁dμ₁ + n₂dμ₂ + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
Finds no application in gas-liquid equilibria involved in distillation
None of these

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Chemical Engineering Thermodynamics
In the reaction, H₂ +I₂ ⇋ 2HI, addition of an inert gas will

Not effect the equilibrium conditions
Increase the partial pressure of H₂
Increase the total pressure and hence shift the equilibrium towards the right
Increase the partial pressure of I₂

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