Mass Transfer
If a two phase system is in physical equilibrium; then it means that, the

Total pressure throughout the liquid phase is equal to that throughout the vapor phase
All of these
Escaping tendency of each component from the liquid phase to the vapor phase is exactly equal to that from vapor phase to liquid phase
Temperature of the liquid phase is equal to that of the vapor phase

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Mass Transfer
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when

Only liquid phase obeys Dalton's law
Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law
Only vapor phase follows Raoult's law
Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law

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Mass Transfer
For water-ethanol system, the minimum reflux ratio

Is computed from the slope of the upper operating line that is tangent to the equilibrium curve
Is the optimum reflux ratio
Is computed from the intercept of the operating line
Cannot be computed

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