Mass Transfer
High pressure at the bottom of a distillation tower handling heat sensitive materials results in

Thermal decomposition of bottoms
Erosion of the tower
Increased relative volatility
Very efficient operation

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Mass Transfer
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when

Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law
Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law
Only vapor phase follows Raoult's law
Only liquid phase obeys Dalton's law

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