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Chemical Reaction Engineering

Chemical Reaction Engineering
Half life period of decomposition of a liquid 'A' by irreversible first order reaction is 12 minutes. The time required for 75% conversion of 'A' is __________ minutes.

12
18
6
24

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Chemical Reaction Engineering
Recycling back of outlet stream to the reactor from an ideal CSTR carrying out a first order liquid phase reaction will result in __________ in conversion.

No change
Either A or B, depends on the type of reaction
Decrease
Increase

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Chemical Reaction Engineering
Calcination reaction of limestone (CaCO₃ → CaO + CO₂) goes to completion in the rotary kiln, because

CaO is not dissociated
CO₂ escapes continuously
Of high calcination temperature
CaO is more stable than CaCO₃

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Chemical Reaction Engineering
Rate constant 'k' and absolute temperature 'T' are related by collision theory (for bimolecular) as

k ∝ T1.5
k ∝ exp(-E/RT)
k ∝ √T
k ∝ T

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Chemical Reaction Engineering
Rate determining step in a reaction consisting of a number of steps in series is the __________ step.

Intermediate
Slowest
Data insufficient; can't be predicted
Fastest

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Chemical Reaction Engineering
For the reaction, A + B → 2B + C,

rA = -rB
rA = 2rB
rA = rB/2
rA = rB

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