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Chemical Reaction Engineering

Chemical Reaction Engineering
From Arhenius law, a plot of loge K versus 1/T gives a straight line with a slope of (-E/R). The unit of E/R is

°K
K cal. °K
K cal
K cal/°K

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Chemical Reaction Engineering
Which of the following is not endothermic in nature?

Gasification of carbon
Combustion of sulphur
Steam reforming of naphtha
Thermal cracking of fuel oil

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Chemical Reaction Engineering
At a given temperature, K₁, K₂ and K3 are equilibrium constants for the following reactions 1, 2, 3 respectively. CH₄(g) + H₂O(g) ⇋ CO(g) + 3H₂(g), CO(g) + H₂O(g) ⇋ CO₂(g) + H₂(g) CH₄(g) + 2H₂O(g) ⇋ CO₂(g) + 4H₂(g) Then K₁, K₂ and K3 are related as:

K3 = K₁.K₂
K3 = (K₁.K₂)2
K3 = (K₁.K₂)0.5
K3(K₁+K₂)/2

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Chemical Reaction Engineering
If helium is introduced in a reactor containing O₂, SO₂ and SO₃ at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO₃ (as per Le Chatlier principle)

Decreases
Changes unpredictably
Increases
Remains unaltered

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Chemical Reaction Engineering
Considering the endotheomic dissociation of CaCO₃ in a closed vessel (CaCO₃ ⇋ CaO + CO₂), the pressure of CO₂ increases, if

A catalyst is added
An inert gas is pumped keeping the temperature constant
The temperature is increased
None of these

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Chemical Reaction Engineering
The conversion for a first order liquid phase reaction. A → B in a CSTR is 50%. If another CSTR of the same volume is connected in series, then the % conversion at the exit of the second reactor will be

75
60
90
100

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