Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Desorption of C
Surface reaction between A in the gas phase and absorbed B
Surface reaction between absorbed A and absorbed B

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Chemical Reaction Engineering
Which of the following is the optimum operating condition for an exothermic reversible reaction taking place in a plug-flow reactor?

Very high temperature should be used throughout the reaction
Very low temperature should be used throughout the reaction
None of these
Temperature should be high in the beginning and decreased towards the end of the reaction

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