Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Surface reaction between A in the gas phase and absorbed B
Surface reaction between absorbed A and absorbed B
Desorption of C
Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase

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Chemical Reaction Engineering
In the converter of the contact process for the manufacture of H₂SO₄ the equilibrium conversion of SO₂ __________ (i) __________ with increase in temperature and __________ (ii) __________ with increase in the mole ratio of SO₂ to air.

(i) increases (ii) decreases
(i) increases (ii) increases
(i) decreases (ii) decreases
(i) decreases (ii) increases

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Chemical Reaction Engineering
Mean residence time is equal to the space time, when

The temperature, pressure and the density of reaction mixture remains constant throughout the reactor
The feed rate is measured at temperature and pressure in the reactor
All of these
There is no change in number of moles in gaseous reaction

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