Mass Transfer
Entrainer used in azeotropic distillation should

Have high latent heat of vaporisation
Form a low boiling azeotrope with one of the constituents of the mixture
Have high viscosity to provide high tray efficiency
Form a new azeotrope of low relative volatility with one of the constituents of the mixture

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Mass Transfer
Fenske's equation for determining the minimum number of theoretical stages in distillation column holds good, when the

Mixture (to be separated) shows negative deviation from ideality
Relative volatility is reasonably constant
Mixture (to be separated) shows positive deviation from ideality
Multicomponent distillation is involved

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