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ELECTROLYSIS AND STORAGE BATTERIES

Electrolysis and Storage Batteries
During the charging and discharging of a nickel-iron cell

nickel hydroxide remains unsplit
water is neither formed nor absorbed
corrosive fumes are produced
its e.m.f. remains constant

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Electrolysis and Storage Batteries
Excessive charging a battery tends to

produce gassing
bring about all above changes
to corrode the positive plates into lead peroxide thereby weakening them physically
increase the internal resistance of the battery

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Electrolysis and Storage Batteries
As compared to constant-current system, the constant-voltage system of charging a lead acid cell has the advantage of

increasing cell capacity
avoiding excessive gassing
reducing time of charging
Both of the listed here

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Electrolysis and Storage Batteries
Charging a sulphated battery at high rate results in

All of the listed here
boiling of electrolyte due to gassing
damage to separators, cell caps covers and battery case due to excessive temperature
warping of plates

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Electrolysis and Storage Batteries
During the idle period of the battery, strong electrolyte tends to change the active material of the cell into

Pb02
Pb
PbSC-4
PbO

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