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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Charles' law for gases states that

V ∝ 1/T
V/T = Constant
V ∝ 1/P
PV/T = Constant

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Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = - nR ln (P₂/P₁), holds good for

Cooling of a real gas
Expansion of a real gas
Reversible isothermal volume change
Heating of an ideal gas

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Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = nR ln (V₂/V₁) + nCv ln (T₂/T₁) is valid for

Heating of a substance
Cooling of a substance
Reversible isothermal volume change
Simultaneous heating and expansion of an ideal gas

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Chemical Engineering Thermodynamics
Which is not constant for an ideal gas?

All of these
(∂P/∂V)T
(∂V/∂T)P
(∂P/∂V)V

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Chemical Engineering Thermodynamics
In the equation PVn = constant, if the value of n = y = Cp/Cv, then it represents a reversible __________ process.

Isentropic
Polytropic
Adiabatic
Isothermal

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Chemical Engineering Thermodynamics
For a spontaneous process, free energy

Increases
Decreases whereas the entropy increases
And entropy both decrease
Is zero

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