Stoichiometry
At standard conditions, N₂ + 2O₂ ⇋ 2NO₂; ΔG° = 100 kJ/moleNO + ½O₂ ⇋ 2NO₂; ΔG° = -35 kJ/moleThe standard free energy of formation of NO in kJ/mole is

30
85
170
15

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Stoichiometry
The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. If, at a total pressure of one standard atm. exerted by the vapours of water and toluene, the mole fraction of water Xw in the vapour phase satisfies

0.5 < Xw < 1.0
Xw = 0.5
0 < Xw < 0.5
Xw = 1.0

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