Chemical Reaction Engineering
At a given temperature, K₁, K₂ and K3 are equilibrium constants for the following reactions 1, 2, 3 respectively. CH₄(g) + H₂O(g) ⇋ CO(g) + 3H₂(g), CO(g) + H₂O(g) ⇋ CO₂(g) + H₂(g) CH₄(g) + 2H₂O(g) ⇋ CO₂(g) + 4H₂(g) Then K₁, K₂ and K3 are related as:

K3(K₁+K₂)/2
K3 = (K₁.K₂)2
K3 = K₁.K₂
K3 = (K₁.K₂)0.5

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Chemical Reaction Engineering
"A spherical porous catalyst particle of radius R is subjected to reactant A which reacts to form B by a zero order surface reaction A → B. Film mass transfer resistance is negligible and pore diffusion of A is rate controlling. The effectiveness factor of the catalyst is reported as 7/8. Which of the following statement is true?A. Inner catalyst core of radius R/8 does not participate in reaction."

Inner catalyst core of radius R/2 does not participate in reaction
Inner catalyst core of radius 7R/8 does not participate in reaction
Ffectiveness factor for a zero order reaction can not be 7/8 as it must always be 1
Inner catalyst core of radius R/8 does not participate in reaction

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