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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
As the temperature is lowered towards the absolute zero, the value of the quantity (∂ΔF/∂T) approaches

Infinity
Zero
Unity
None of these

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Chemical Engineering Thermodynamics
Joule-Thomson effect i.e., a throttling process is a constant __________ process.

Enthalpy
Internal energy
Temperature
Entropy

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Chemical Engineering Thermodynamics
In case of a close thermodynamic system, there is __________ across the boundaries.

No heat and mass transfer
Mass and energy transfer
None of these
No mass transfer but heat transfer

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Chemical Engineering Thermodynamics
A solute distributes itself between two non-miscible solvents in contact with each other in such a way that, at a constant temperature, the ratio of its concentrations in two layers is constant, irrespective of its total amount". This is

The distribution law
None of these
A corollary of Henry's law
Followed from Margule's equation

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Chemical Engineering Thermodynamics
Critical compressibility factor for all substances

None of these
Are more or less constant (vary from 0.2 to 0.3)
Vary as square of the absolute pressure
Vary as square of the absolute temperature

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Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

2 RT
-RT ln 0.5
-2 RT ln 0.5
0.5 RT

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