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Chemical Reaction Engineering

Chemical Reaction Engineering
A liquid decomposes by irreversible first order kinetics and the half life period of this reaction is 8 minutes. The time required for 75% conversion of the liquid will be __________ minutes.

4
16
8
12

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Chemical Reaction Engineering
A catalyst in a chemical reaction __________ free energy change in the reaction.

Neither A nor B
Either A or B; depends on the type of catalyst
Increases
Decreases

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Chemical Reaction Engineering
With increase in initial concentration, the fractional conversion of a first order reaction in a given time

Increases
Remains constant
Unpredictable
Decreases

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Chemical Reaction Engineering
Overall rate of reaction in a heterogenous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of catalyst, if it does not entail a chain mechanism.

Independent of
Proportional to the square of
Inversely proportional to
Proportional to

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Chemical Reaction Engineering
Space time equals the mean residence time

For CSTR
For narrow diameter tubular reactor
For large diameter tubular reactor
When the density of the reaction mixture is constant

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Chemical Reaction Engineering
Consider the 'n' th order irreversible liquid phase reaction A → B. Which one of the following plots involving half life of the reaction (t1/2) and the initial reactant concentration (CA0) gives a straight line plot?

Ln CA0 Vs t1/2
Ln CA0 Vs ln t1/2
CA0 Vs t1/2
CA0 Vs ln t1/2

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