Mass Transfer
A distillation column with N plates is being operated under normal conditions. At some point of time, the operation is shifted to total reflux condition (i.e., no product and residue are being withdrawn and feed to the column is stopped). At the new steady state,

The top and bottom compositions are unchanged with and without total reflux
Reboiler load and condenser load are minimum
The top and bottom compositions correspond to the maximum enrichment available
Composition of vapors and that of liquid do not vary throughout the column

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Mass Transfer
To get high tray efficiency

Gas velocity should be very low
Interfacial surface between liquid and gas phase should be large
Time of contact between the two phases should be less
Liquid entrainment should be severe

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Mass Transfer
In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because

Mixing of steam with the material being vaporised is not so intimate as to result in equilibrium condition
Total pressure is less
Saturated steam is used for steam distillation
Temperature is less

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