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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
A chemical reaction will occur spontaneously at constant pressure and temperature, if the free energy is

None of these
Positive
Zero
Negative

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Chemical Engineering Thermodynamics
For a thermodynamic system containing 'x' chemical species, the maximum number of phases that can co-exist at equilibrium is

X + 3
X + 2
X
X + 1

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Chemical Engineering Thermodynamics
Heat is added at constant pressure in an ideal __________ cycle.

Brayton
Stirling
Both B and C
Rankine

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Chemical Engineering Thermodynamics
Pressure-enthalpy chart is useful in refrigeration. The change in internal energy of an ideal fluid used in ideal refrigeration cycle is

Zero
Positive
Infinity
Negative

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Chemical Engineering Thermodynamics
The reaction A (l) R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The number of degrees of freedom are

3
2
1

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Chemical Engineering Thermodynamics
Cp of a gas at its critical temperature and pressure

Becomes infinity
Equals 1 kcal/kmol °K
Equals 0.24 kcal/kmol °K
Becomes zero

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