Fuels and Combustion
A carbonaceous fuel (containing no H₂ or hydrocarbons) is burnt and the resulting flue gas contains 21% CO₂. It means that

21% excess oxygen has been used for combustion
21% excess air has been used for combustion
No excess air has been used for combustion
Complete combustion of fuel has taken place

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Fuels and Combustion
Fuel gases containing hydrocarbons (ie.g. coke oven gas) are not preheated before burning, mainly because

It reduces its calorific value tremendously
It reduces its flame temperature tremendously
The hydrocarbons crack thereby choking and fouling the heat transfer surface by carbon soot
There are chances of explosion during preheating

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